Tech Support: Can I transfer my existing Windows 8.1, my programs and Docs easily to a new SSD with a cable before installing it?

Can I transfer my existing Windows 8.1, my programs and Docs easily to a new SSD with a cable before installing it?

I just bought an ACER Aspire ZC-102 All-In-One.
I've upgraded the Win8 to 8.1.
I've installed my Office 2003 and the Outlook PST data file, Paint Shop Pro, cCleaner, Revo Uninstaller Pro, etc.
I'm still trying to get my OmniPass password software to work on 8.1 and THAT has been a challenge in trying to import my big profile of saved sites, user names and passwords.
I've asked Softex for help on that.
I've also been struggling getting my SyncBack SE to sync this new pc with my other desktop WinXP machine's My Docs.
Seems to be some Access Denied issue that I haven't been able to figure out.
Anyway, is there a somewhat easy way to connect an SSD drive (which I know nothing about) and just transfer an image of my current hard drive to it without needing to start over with a clean install?
ACER tells me that I can by an SSD to increase my RAM from the 4 GB on it up to 16 GB and I see one at

www.crucial.com/store/listparts.aspx?model=aspire+zc-102-ur20 for about $157.

Anwsers to the Problem Can I transfer my existing Windows 8.1, my programs and Docs easily to a new SSD with a cable before installing it?

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If you failed to fix it, another option is to call Microsoft and walk through the process with a technician. To do this, dial "1-800-936-5700". Explain the error that you received and the steps in the update process during which it was displayed. The technician will be able to walk through the steps from getting a new product key to finishing the installation.

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